Methane steam reforming reaction in solid oxide fuel cells: Influence of electrochemical reaction and anode thickness

نویسندگان

چکیده

The influence of operation temperature, inlet gas composition, current density and the anode thickness on methane steam reforming reaction over nickel yttria-stabilized zirconia anodes was experimentally studied in solid oxide fuel cells. experimental results were analyzed using data fitting Power-Law Langmuir–Hinshelwood kinetic models. Similar trends dependence partial pressures observed both order is positive. Negative pressure rate are found. electrochemical affect kinetics parameters. shows particular influences order, activation energy when a produced. model evaluation suggests that two models comparable extra parameters within contributing to lower mean absolute percentage error higher coefficient determination R2.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Simulation of a Solid Oxide Fuel Cell with External Steam Methane Reforming and Bypass

Fuel flexibility is a significant advantage of solid oxide fuel cells (SOFCs) and can be attributed to their high operating temperature. The eligibility of a combined heat and power (CHP) system has been investigated as a new power generation methode, in this study. Natural gas fueled SOFC power systems via methane steam reforming (MSR) yield electrical conversion efficiencies exceeding 50% and...

متن کامل

Enhanced methane steam reforming activity and electrochemical performance of Ni0.9Fe0.1-supported solid oxide fuel cells with infiltrated Ni-TiO2 particles

Ni0.9Fe0.1 alloy-supported solid oxide fuel cells with NiTiO3 (NTO) infiltrated into the cell support from 0 to 4 wt.% are prepared and investigated for CH4 steam reforming activity and electrochemical performance. The infiltrated NiTiO3 is reduced to TiO2-supported Ni particles in H2 at 650 °C. The reforming activity of the Ni0.9Fe0.1-support is increased by the presence of the TiO2-supported ...

متن کامل

Importance of Anode Microstructure in Modeling Solid Oxide Fuel Cells

A one-dimensional button-cell model is developed and applied to explore the influence of anode microstructure on solid oxide fuel cell (SOFC) performance. The model couples porous-media gas transport and elementary electrochemical kinetics within a porous Ni-YSZ cermet anode, a dense YSZ electrolyte membrane and a composite LSM-YSZ cathode. In all cases the fuel is humidified H2 and air is the ...

متن کامل

Electrochemical Study of Hydrogen Adsorption/Reduction (HAR) Reaction on Graphene Oxide as Electrocatalyst for Proton Exchange Membrane Fuel Cells

In the current work, graphene oxide (GO) samples were prepared at room temperature from graphite flakes using a modified Hummer's method to produce metal-free electrocatalysts. The effect of the duration of the oxidation process on the structural, chemical and physical characteristics of the GO samples was evaluated using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), ...

متن کامل

Optimization of the Interconnect Ribs for a Cathode-Supported Solid Oxide Fuel Cell

A comprehensive mathematical model of the performance of the cathode-supported solid oxide fuel cell (SOFC) with syngas fuel is presented. The model couples the intricate interdependency between the ionic conduction, electronic conduction, gas transport, the electrochemical reaction processes in the functional layers and on the electrode/electrolyte interfaces, methane steam reforming (MSR) and...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Power Sources

سال: 2021

ISSN: ['1873-2755', '0378-7753']

DOI: https://doi.org/10.1016/j.jpowsour.2021.230276